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Synthesis of (.+-.)-Solanapyrones A and B.

✍ Scribed by Barry Lygo; Mohamed Bhatia; Jason W. B. Cooke; David J. Hirst

Publisher
John Wiley and Sons
Year
2003
Weight
168 KB
Volume
34
Category
Article
ISSN
0931-7597

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Synthesis of (Β±)-solanapyrones A and B
Synthesis of (Β±)-solanapyrones A and B
✍ Barry Lygo; Mohamed Bhatia; Jason W.B. Cooke; David J. Hirst πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 293 KB

In this paper we report the development of a stereoselective IMDA approach to the phytotoxic polyketides (Β±)-solanapyrones A and B. The stereoselectivity of the key IMDA cycloaddition was optimized by investigating a range of 2,8,10-dodecatrienoic acid derivatives. This established that use of the W

Synthesis of (Β±)-solanapyrone A
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✍ Akitami Ichihara; Masayoshi Miki; Hiroyuki Tazaki; Sadao Sakamura πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 209 KB

The first synthesis of solanapyrone A m, a phytotoxin from Alternaria solani, has been completed through the intramolecular Diels-Alder reaction. Solanapyrone A (1) is a principal phytotoxin recently isolated along with other metabolites, solanapyxnes B &, C k)' and zinnolide', from the culture brot