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Synthesis of silylated methylenecyclopropanes

✍ Scribed by Ethan Sternberg; Paul Binger


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
215 KB
Volume
26
Category
Article
ISSN
0040-4039

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Facile synthesis of silylated thioglycos
✍ Sudhir Nambiar; John F. Daeuble; Ronald J. Doyle; K. Grant Taylor πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 264 KB

The one pot conversion of 1,2,4,6-tetra-O-acetyl-B-D\_glucopyranose, 1, into phenyl 2,4,6-tri-0-acetyl-3-0-trialkylsilyl-l-thio-~-~-glucopyranosides, 3, is described. The method is applicable to use with galactopyranosyl-, 2-deoxyglucopyranosyl-, and ribofuranosyl-starting materials.