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Synthesis of (±) silphinene

✍ Scribed by Y. Koteswar Rao; M. Nagarajan

Book ID
103399877
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
148 KB
Volume
29
Category
Article
ISSN
0040-4039

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Total synthesis of (±)-silphinene
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The easily accessible alcohol 2 is oxidized. after protection, to the allylic alcohol 3. The bensyl ether of this diquinonic alcohol is tran&omted into the tn~quinanic precursor 9 of(+) Silphinene, wing a similar reaction sequence as described previously, but using the opposite epimer.