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Synthesis of silicohydrocarbons fromβ-silicohalides and alkyl-lithium

✍ Scribed by A. D. Petrov; V. P. Lavrischchev

Book ID
112491549
Publisher
Springer
Year
1952
Tongue
English
Weight
265 KB
Volume
1
Category
Article
ISSN
1573-9171

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✍ Tsujiaki Hata; Masashi Nakajima; Mitsuo Sekine 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 210 KB

8-Alkyl-substituted carboxylates were synthesized in good yields from U,B-unsaturated aldehydes by using the 1:l carbonyl adducts with diethyl bis(trimethylsily1) phosphite. Recently, several studies on acyl anion equivalents utilizing carbonyl insertion reactions have appeared. 2 It has been report