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Synthesis of silica-supported bidentate arsine palladium complex and its catalytic properties for amidation/butoxycarbonylation of aryl halides

โœ Scribed by Mingzhong Cai; Yizheng Huang; Ronghua Hu; Caisheng Song


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
74 KB
Volume
212
Category
Article
ISSN
1381-1169

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Synthesis of silica-supported poly-ฮณ-dip
โœ Mingzhong Cai; Yizheng Huang; Ronghua Hu; Caisheng Song ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 68 KB

A silica-supported poly-โฅ-diphenylarsinopropylsiloxane palladium complex has been prepared from โฅ-chloropropyltriethoxysilane via immobilization on fumed silica, followed by reacting with potassium diphenylarsenide in THF and then the reaction with palladium chloride. It is an efficient catalyst for