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Synthesis of Selectively Protected Genistein Derivatives.

✍ Scribed by Wieslaw Szeja; Gabriela Pastuch; Ilona Wandzik; Nikodem Kuznik; Grzegorz Grynkiewicz


Publisher
John Wiley and Sons
Year
2004
Weight
50 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The proline‐catalysed aldol reaction of 2,2‐dimethyl‐1,3‐dioxan‐5‐one with dimethoxyacetaldehyde is used as the key reaction according to the biomimetic C~3~+C~n~ strategy for __de novo__ carbohydrate synthesis. Based on the Whitesides inversion strategy, protected D‐__erythro__‐pentos‐