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Synthesis of secondary alkylamines from aliphatic alcohols and primary amines

✍ Scribed by Yu.B. Kagan; A.N. Bashkirov; G.A. Kliger; Lyui Guan-Yui

Book ID
116041464
Publisher
Elsevier Science
Year
1963
Weight
550 KB
Volume
2
Category
Article
ISSN
0031-6458

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## Abstract The chemoselective __N__‐alkylation of __tert__‐alkylamines applying aliphatic amines is described for the first time. In the presence of the Shvo catalyst **1**, __tert__‐octylamine **4** and 1‐adamantylamine **5** are alkylated using primary, secondary, and even tertiary amines to giv