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Synthesis of S, N-ketenacetals from β-dicarbonyl compounds and methyl thiocyanate

✍ Scribed by V. A. Dorokhov; M. F. Gordeev

Book ID
112539875
Publisher
Springer
Year
1988
Tongue
English
Weight
89 KB
Volume
37
Category
Article
ISSN
1573-9171

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The iodocyclization of a series of alkenyl-substituted p-enamino esters and ketones, followed by base-promoted dehydroiodination, led to the formation of the corresponding pyrrole or tetrahydroindole derivatives. In the absence of base, the iodo-I~-enamino esters 5 and 7 underwent spontaneous aromat