Synthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketones
✍ Scribed by Dayan, Serkan; Kayacı, Nilgün; Kalaycioglu, Nilgun Ozpozan; Dayan, Osman; Çırçır Öztürk, Esra
- Book ID
- 120517757
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 845 KB
- Volume
- 401
- Category
- Article
- ISSN
- 0020-1693
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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the
We developed an efficient, easily available, and easy to use proline amide-based ruthenium(II) catalysts for the asymmetric hydride transfer reduction of prochiral ketones and e.e.s up to 98.8% have been measured.