Electrophilic additions / Bromine addition to double bonds / Hydrogenation of double bonds / Rotaxanes / Supramolecular chemistry Here we report on the possibility of using rotaxane wheels free axle compounds 6a and 6b, indicating steric hindrance of the C=C double bond by the wheel of the rotaxane
Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components
✍ Scribed by Dr. Mirko Händel; Dipl.-Chem. Marcus Plevoets; Dipl.-Chem. Sven Gestermann; Prof. Dr. Fritz Vögtle
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 419 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
constant I Mechanical bonding I Molecular recognition I Template synthesis / Supramolecular chemistry The first synthesis of amide-linked rotaxanes with non-arene axle building blocks is reported. The threading synthesis of rotaxane 8 with olefinic fumaryl chloride proves that arene moieties are no
## Abstract The new π‐donor/π‐acceptor type rotaxanes 15, 16 bearing chiral sugar units as blocking groups have been synthesized in 2% and 6% yield, starting from acetobromo glucose 10 and the podands 8 or 9, followed by the reaction of the resulting axles 11 and 12 with the dicationic bis(bipyridi