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Synthesis of Rhenium(I) Tricarbonyl Complexes with Carbohydrate-Pendant Tridentate Ligands and Their Cellular Uptake

โœ Scribed by Yuji Mikata; Kyoko Takahashi; Yuka Noguchi; Masami Naemura; Anna Ugai; Saori Itami; Keiko Yasuda; Satoshi Tamotsu; Takashi Matsuo; Tim Storr


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
957 KB
Volume
2012
Category
Article
ISSN
1434-1948

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The organorhodium(I) complexes [Rh(PNP)R] [PNP = 2,6-stable monohydridorhodium(III) complex [Rh(PNP)ClH-(CH 3 CN)]SO 3 CF 3 (7) was obtained by the reaction of bis(diphenylphosphanylmethyl)pyridine, R = CH 3 (3a), C 6 H 5 (3b)] were synthesized from [Rh(PNP)(C 2 H 4 )]BF 4 (1a) and LiR [Rh(PNP)Cl] w