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Synthesis of Reactive Amphiphilic Copolymers Based on Oligoglycidol Macromonomers

✍ Scribed by Sascha Pargen; Jürgen Omeis; Guillaume Jaunky; Helmut Keul; Martin Möller

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
316 KB
Volume
212
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Various linear and branched oligoglycidol macromonomers are prepared using anionic ring opening polymerization of the monomers ethoxyethyl glycidyl ether (EEGE) and glycidol. Starting with 4‐vinyl benzyl alcohol (VBA), allyl glycol or N‐(2‐hydroxyethyl) methacryl amide (HEMAm) oligoglycidol macromomonomers with three to six repeating units are obtained in good yields and characterized with NMR, SEC, DSC and TGA. These macromonomers are versatile tools and can be used as prepolymers for the synthesis of reactive amphiphilic copolymers. The successful conversion of the macromonomers to copolymers via radical polymerization is demonstrated. magnified image

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