Synthesis of racemic hotrienol and santolina alcohol from cyclopropenes
β Scribed by B. A. Cheskis; A. M. Moiseenkov; T. Yu. Rudashevskaya; O. A. Nesmeyanova
- Book ID
- 112447736
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 388 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Successive treatment of propargylic carbonates or phosphates with a Ti(O-i-Pr)4/2i-PrMgC1 reagent and dialkyl azodicarboxylates gave ct-hydrazinoalkynes in good yields. The reaction, which proceeded with up to 86% chiral transfer, thus has opened up a new route to optically active ct-hydrazinoalkyne
## Abstract A stereoselective fourβstep synthesis of racemic patchouli alcohol starting from the known 2,6,6βtrimethylβ2,4βcyclohexadienβ1βone [1] and 3βmethylpentβ4βenβ1βol [2] is described.