Synthesis of rac-(E)-Opposita-4(15),7(11)-dien-12-al. -The title sesquiterpene aldehyde (XIII) is prepared starting from commercially available methylcyclohexenone (I) via a diastereoselective tandem alkylation of compound (I), a chemoselective hydroboration of vinyl group in compound (V) and a Wit
Synthesis of rac-(E)-Opposita-4(15),7(11)-dien-12-al
β Scribed by Peter Weyerstahl; Helga Marschall; Peter Degenkolb; Philippine Lebada
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 219 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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β¦ Synopsis
E)-Opposita-4(15),7(11)-dien-12-al / Natural products / Vetiver oil / Octahydroindene derivatives / Fragrances rac-(E)-Opposita-4(15),7(11)-dien-12-al (1) was synthesized Vetiver oil. Synthetic rac-1 has a strong, green woody odor with soft-floral undertones, which confirms that 1 is an in 12 steps via the aldehyde 11 as the key compound. The spectroscopic data of rac-1 are identical with those of the olfactorily important constituent of Vetiver oil. corresponding natural product, previously isolated from
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