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Synthesis of R -(−)-Imperanene from the Natural Lignan Hydroxymatairesinol

✍ Scribed by Eklund, Patrik C.; Riska, Annika I.; Sjöholm, Rainer E.

Book ID: 120630328
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 59 KB
Volume: 67
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo025985c

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## Abstract The structures of TADDOL‐like α‐conidendrin‐based chiral 1,4‐diols (LIGNOLs) have been studied at molecular mechanics, Hartree‐Fock (HF)/6‐31G\* and DFT/B3LYP/TZVP level of theory. The molecules included were 1,1‐diphenyl, two diastereomers of 1,1,4‐triphenyl, 1,1,4,4‐tetraphenyl, and 1