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Synthesis of R-(-)-2-Ethyl-N-benzyl (monoaza-15-crown-5) and the Crystal Structure of Its Sodium Perchlorate Complex

✍ Scribed by Süheyla Özbey; Halil Hoşgören; Yilmaz Turgut; Giray Topal


Book ID
110298342
Publisher
Springer Netherlands
Year
2001
Tongue
English
Weight
105 KB
Volume
39
Category
Article
ISSN
0923-0750

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Preparation of N-(4′,6′-difluoro-2′-hydr
✍ Yoichi Habata; Sadatoshi Akabori 📂 Article 📅 2001 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Armed monoaza‐15‐crown‐5 having a 4′,6′‐difluoro‐2′‐hydroxybenzyl group as an additional binding site (**2**) has been prepared by the Mannich reaction of __N__‐methoxymethylmonoaza‐15‐crown‐5 with 3,5‐difluorophenol. The reactive site on 3,5‐difluorophenol for the Mannich reaction was