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Synthesis of Pyrrolidines and Pyrroles by Tandem Amination/Cyanation/Alkylation and Amination/Oxidation Sequences

✍ Scribed by Han, Junbin; Lu, Zhichao; Hammond, Gerald B.; Xu, Bo

Book ID
126948216
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
377 KB
Volume
2014
Category
Article
ISSN
1434-193X

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✍ Richard A. Bunce; Derrick M. Herron; Jason R. Lewis; Sharadsrikar V. Kotturi 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 68 KB

## Abstract __N__‐Phenyl‐substituted pyrrolidines and piperidines have been synthesized by catalytic reduction of nitrobenzene in the presence of 4‐ and 5‐oxoaldehydes, respectively. The process involves reduction of the aromatic nitro group to give the __N__‐phenylhydroxylamine or aniline followed