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Synthesis of Pyridine−Borane Complexes via Electrophilic Aromatic Borylation

✍ Scribed by Ishida, Naoki; Moriya, Taisaku; Goya, Tsuyoshi; Murakami, Masahiro

Book ID
120257980
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
1014 KB
Volume
75
Category
Article
ISSN
0022-3263

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Synthesis of Pyridine−Borane Complexes v
Synthesis of Pyridine−Borane Complexes via Electrophilic Aromatic Borylation
✍ Ishida, Naoki; Moriya, Taisaku; Goya, Tsuyoshi; Murakami, Masahiro 📂 Article 📅 2010 🏛 American Chemical Society 🌐 English ⚖ 1014 KB

Pyridine-borane complexes were synthesized from 2-arylpyridines through an electrophilic aromatic borylation reaction with BBr 3 . The intermediate 2-(2-dibromoborylaryl)pyridines were stable enough to be handled in air and served as the synthetic platform for variously substituted pyridine-borane c