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Synthesis of pyridine fused polycyclic amines using sequential ring-closing metathesis and radical cyclisation reactions

✍ Scribed by S.Richard Baker; Manuel Cases; Martine Keenan; Richard A. Lewis; Paul Tan

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 299 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00389-7

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✦ Synopsis

The syntheses of novel pyridine fused polycyclic bridgehead amines are described using sequential ring-closing metathesis (RCM) and 5-exo-trig intramolecular radical cyclisation reactions. Critical to the success of the two sequential steps were the RCM catalyst and/or the nature of the nitrogen atom.

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