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Synthesis of Pyrazole Derivatives and Their Evaluation as Photosynthetic Electron Transport Inhibitors

โœ Scribed by Vicentini, Chiara B.; Mares, Donatella; Tartari, Alfredo; Manfrini, Maurizio; Forlani, Giuseppe


Book ID
120006174
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
235 KB
Volume
52
Category
Article
ISSN
0021-8561

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## Abstract The glucoseโ€, mannoseโ€, and galactoseโ€derived spirocyclic cyclopropylammonium chlorides **1a**โ€“**1d, 2a**โ€“**2d** and **3a**โ€“**3d** were prepared as potential glycosidase inhibitors. Cyclopropanation of the diazirine **5** with ethyl acrylate led in 71% yield to a 4โ€‰:โ€‰5โ€‰:โ€‰1โ€‰:โ€‰20 mixture