Synthesis of protected myo-inositols
β Scribed by Ian H. Gilbert; Andrew B. Holmes; Rodney C. Young
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 133 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The syntheses are described of the 1-O-carbamoyl (11), 1-O-carbamoyl-2-O-stearoyl (10), 1-O-(acetylcarbamoyl)-2-O-stearoyl (12), 1-O-(heptylcarbamoyl) (13), 2-O-(heptylcarbamoyl) (14) 1,2-di-O-(heptylcarbamoyl) (15), and 1-O-(octadecylcarbamoyl) (16) derivatives of myo-inositol. None of these compou
The synthesis of the optically pure 1,4,5,6-tetra-O-benzyl-myo-inositols was achieved in four steps via diastereomeric 2,3-spire-acetals of myo-inositol with Land D-camphor as the key intermediates. Camphor dimethyl acetal was used for the acetalation reaction. The diastereomers were benzylated and