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Synthesis of proline fullerene derivative

✍ Scribed by Yilei Zhao; Liangbing Gan; Dejian Zhou; Chuping Luo; Chunhui Huang; Guocheng Jia; Wu Tie


Book ID
105641144
Publisher
Springer
Year
1997
Tongue
English
Weight
240 KB
Volume
42
Category
Article
ISSN
1001-6538

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Starting from trans-4-hydroxy-L-proline, a polyfluorinated proline derivative having a fluorine content of 54% has been prepared. It has been tested as a catalyst in the aldol reaction between p-nitrobenzaldehyde and acetone with 73% ee in BTF and in copper(I)-catalyzed allylic oxidation of cyclohex