Synthesis of preparative concentrations of Nb(III) in formamide and dimethylformamide solutions
✍ Scribed by R. Bosselaar; F. Berendes; R. Glaser
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 129 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-1650
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Ahstraet-The electro-oxidation of formic acid and its derivatives-formamide and dimethylformamid~has been studied at a porous platinum electrode in 0.05M H,SO, with special attention to common features of their electrochemical behaviour. It is shown that the contribution of bulk reactions to the ele
## Abstract High‐pressure ^1^H‐NMR. has been used to determine volumes of activation (Δ__V__#) for solvent exchange with [M(S)~6~]^3+^ ion (M = Al(III), Ga(III); S = dimethylsulfoxide (DMSO) and __N,N__‐dimethylformamide (DMF)) in [^2^H]~3~‐nitromethane solution. For Al(III),Δ __V__# = + 15.6 ± 1.4