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Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins

✍ Scribed by E Rose; M Quelquejeu; R.P Pandian; A Lecas-Nawrocka; A Vilar; G Ricart; J.P Collman; Z Wang; A Straumanis

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 364 KB
Volume: 19
Category: Article
ISSN: 0277-5387
DOI: 10.1016/s0277-5387(99)00413-1

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✦ Synopsis

Porphyrins, with two chiral binaphthyl handles, efficiently catalyze the epoxidation of terminal olefins to give epoxides with high enantiomeric excess and turnover number.

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