Synthesis of porphyrazines bearing thioalkylthiol tethers: useful building blocks for supramolecular chemistry

✍ Scribed by Daniela Pietrangeli; Giampaolo Ricciardi

• Book ID: 104098795
• Publisher: Elsevier Science
• Year: 2011
• Tongue: French
• Weight: 395 KB
• Volume: 52
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/j.tetlet.2010.12.103

✦ Synopsis

A simple and substantially inexpensive method is proposed for the synthesis of a porphyrazine macrocycle symmetrically functionalized with eight bromoalkylthio pendants and its conversion in the S-acetyl protected thiol-hexylthio-substituted analog.