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Synthesis of poly(vinylamine) containing asymmetric nucleic acid base derivatives as grafted pendants

✍ Scribed by Overberger, C. G. ;Kikyotani, S.


Publisher
John Wiley and Sons
Year
1983
Weight
33 KB
Volume
21
Category
Article
ISSN
0360-6376

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Synthesis of poly(vinylamine) containing
✍ Overberger, C. G. ;Kikyotani, S. πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons βš– 763 KB

## Abstract The preparations of new model polymers of polynucleotides with stereoregular poly(vinylamine) (PVAm) backbones and an optically active nucleic acid base derivative as a pending side chain are described. The grafting of (Β±)‐, (+)‐, and (βˆ’)‐2‐(thymin‐1‐yl) propionic acid to linear PVAm pr

Spectroscopic studies of poly(vinylamine
✍ Overberger, C. G. ;Kikyotani, S. πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons βš– 891 KB

## Abstract The optical properties of poly(vinylamine) containing optically active (+)‐ or (βˆ’)‐2‐(thymin‐1‐yl) propionyl groups as grafted pendants (PT) and the related monomer (MT) and dimer models (DT) were investigated by UV, circular dichroism (CD), and NMR spectroscopy. Highly syndiotactic PT