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Synthesis of polyvinylamine and polymer analogous reactions

✍ Scribed by Thomas Fischer; Walter Heitz

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
408 KB
Volume
195
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Polyvinylamine (PVVAm) was synthesized using the precursor poly(tert‐butyl N‐vinylcarbamate) (PTBNVC). The monomer synthesis was improved, and the control of the molecular weight of the PTBNVC and the PVAm by a transfer reaction with the solvent is demonstrated. TBNVC was radically polymerized. In suspension polymerization molecular weights of 10^6^ g/mol are accessible. Different polymer analogous reactions were carried out. The resulting polymers are methylated polyvinylamine, poly(N‐vinylureas), poly(N‐vinylalkanamides) and PVAm‐adducts with acrylic acid derivatives.

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