Various segmented polyurethane materials with a polyurethane hard segment (HS) content of 40 wt % were prepared by bulk polymerization of a poly(tetramethylene ether) glycol with M n of 2000, 1,4-butanediol, and various diisocyanates. The diisocyanates used were pure 4,4Π-diphenylmethane diisocyanat
Synthesis of polyurethanes from fluorinated diisocyanates
β Scribed by Hollander, Jerome ;Trischler, Floyd D. ;Gosnell, Rex B.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1967
- Tongue
- English
- Weight
- 600 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0449-296X
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## Abstract A fluorene diol derivative, 9,9β__bis__[4β(2βhydroxyethoxy)phenyl]fluorene (**1**), reacted with diisocyanates such as 1,3β__bis__(isocyanatomethyl)cyclohexane (**2a**), 1,6βdiisocyanatohexane (**2b**), and 1,3β__bis__(isocyanatomethyl)benzene (**2c**) under temperatureβcontrolled micro