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Synthesis of polypropylene oligomer—clay intercalation compounds

✍ Scribed by Makoto Kato; Arimitsu Usuki; Akane Okada

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
156 KB
Volume
66
Category
Article
ISSN
0021-8995

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✦ Synopsis

The synthesis of polypropylene (PP) oligomer-clay intercalation compounds was studied by using three kinds of PP oligomers and organophylic clay. PP oligomers were two types of maleic-anhydride-modified PP oligomers containing different amount of maleic anhydride groups and one type of hydroxy modified PP oligomer. Organophylic clay was sodium-ion-exchanged montmorillonite with octadecylammonium ion (C18-Mt). PP oligomer was mixed with C18-Mt at 200ЊC. Maleic-anhydridemodified PP oligomer, which was of high acid value type, and hydroxy-modified PP oligomer were intercalated between silicate layers of clay; and PP oligomer-clay intercalation compounds were synthesized successfully. But maleic-anhydride-modified PP oligomer, which was of low acid value type, was not intercalated.

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