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Synthesis of polynitro and azido diesters of pentacyclo[4.3.0.0 2,5 .0 3,8 .0 4,7 ]nonane-2,4-dicarboxylic acid

✍ Scribed by Guan, Xiao-Pei; Su, Zhuang; Du, Jian-Wei; Sun, Jian-Guang; Yu, Yong-Zhong

Book ID: 126542618
Publisher: Taylor and Francis Group
Year: 1997
Tongue: English
Weight: 325 KB
Volume: 15
Category: Article
ISSN: 0737-0652
DOI: 10.1080/07370659708216078

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## Abstract The synthesis of 2,7,9‐trimethylenetricyclo[4.3.0.0^3,8^]nonane (8), 7,9‐dimethylenetricyclo[4.3.0.0^3,8^]nonan‐2‐one (15), and 2,9‐dimethylenetricyclo[4.3.0.0^3,8^]non‐4‐ene (9) has been achieved. The first key step of the synthesis is a Diels‐Alder reaction. In the reaction sequence a