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Synthesis of polymers having arylene-vinylene units by palladium-catalyzed hydroarylation polymerization of diethynylbenzene derivatives

✍ Scribed by Cheol-Kyu Choi; Ikuyoshi Tomita; Takeshi Endo


Book ID
106002631
Publisher
Springer
Year
2000
Tongue
English
Weight
109 KB
Volume
44
Category
Article
ISSN
0170-0839

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Regiocontrolled polymer (2) having 2-naphthol unit was prepared by oxidative coupling polymerization of bis(2-naphthol) (1). Polymerizations were conducted in dichloromethane in the presence of [di--hydroxo-bis(N,N,NЈ,NЈ-tetramethylethylenediamine)copper(II)] chloride [CuCl(OH)TMEDA] under air at ro