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Synthesis of Polyhydroxylated 6-N-Benzylpiperidin-2-Ones. A Novel Access to 1, 5-Dideoxy-1, 5-imino-D-xylitol

✍ Scribed by Boyer, Francęois-Didier ;Pancrazi, Ange ;Lallemand, Jean-Yves


Book ID
120529564
Publisher
Taylor and Francis Group
Year
1995
Tongue
English
Weight
413 KB
Volume
25
Category
Article
ISSN
0039-7911

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By an Amadori rearrangement of easily available 5-azido-5-deoxy-D-glucofuranose with dibenzylamine and subsequent catalytic hydrogenation of the resulting 5-azido-l-dibenzylamino-l,5dideoxy-D-fructopyranose, the new l-amino-l,2,5-trideoxy-2,5-ilnino-D-mannitol was obtained in only two steps and exce