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Synthesis of Polyfunctional Allenes by Successive Copper-Mediated Substitutions

✍ Scribed by Matthias A. Schade; Dr. Shigeyuki Yamada; Prof. Dr. Paul Knochel


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
272 KB
Volume
17
Category
Article
ISSN
0947-6539

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✍ Ioannis Sapountzis; Henry Dube; Paul Knochel 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

## Abstract The iodine‐magnesium exchange reaction allows the preparation of polyfunctional arylmagnesium species bearing a nitro group in the __ortho__‐position. After transmetalation to the corresponding arylzinc compound, these organometallics undergo a palladium‐catalyzed Negishi cross‐coupling