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Synthesis of poly(ethylene oxide) with heterobifunctional reactive groups at its terminals by an anionic initiator

โœ Scribed by Yokoyama, Masayuki; Okano, Teruo; Sakurai, Yasuhisa; Kikuchi, Akira; Ohsako, Nobuyuki; Nagasaki, Yukio; Kataoka, Kazunori


Book ID
120655128
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
233 KB
Volume
3
Category
Article
ISSN
1043-1802

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Synthesis of poly(ethylene oxide) with a
โœ Martin Mosquet; Yves Chevalier; Pierre Le Perchec; Jean-Pierre Guicquero ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 819 KB

## Abstract Poly(ethylene oxide)s having a primary or secondary amino group at one chain end have been synthesized by direct anionic polymerization of ethylene oxide initiated by aminoalcoholates. The ring opening reaction of ethylene oxide by the amino group could be avoided when the alcoholate wa