This paper discusses the poly(ethylene-co-p-methylstyrene) copolymers prepared by metallocene catalysts, such as Et(Ind) 2 ZrCl 2 and [C 5 Me 4 (SiMe 2 N t Bu)]-TiCl 2 , with constrained ligand geometry. The copolymerization reaction was examined by comonomer reactivity (reactivity ratio and comonom
β¦ LIBER β¦
Synthesis of poly(ethylene-co-p-methylstyrene) copolymers by metallocene catalysts with constrained ligand geometry
β Scribed by T. C. Chung; H. L. Lu
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 117 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0887-624X
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This paper discusses the copolymerization reaction of propylene and pmethylstyrene (p-MS) via four of the best-known isospecific catalysts, including two homogeneous metallocene catalysts, namely, {SiMe 2 [2-Me-4-Ph(Ind)] 2 }ZrCl 2 and Et(Ind) 2 ZrCl 2 , and two heterogeneous Ziegler-Natta catalysts