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Synthesis of polyetherols with purine ring. Kinetics and mechanisms of reactions, part 2: Reactions in the presence of triethylamine

✍ Scribed by Irmina Cisek-Cicirko; Jacek Lubczak

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
179 KB
Volume
37
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The kinetics and mechanism of reaction between hydroxymethyl derivatives of uric acid and oxiranes in the presence of triethylamine as catalyst was studied. The formation of polyetherols was inhibited in initial steps of the reaction. Two different mechanisms were established for the reactions in which intermediates contained O‐hydroxymethyl and O‐(2‐hydroxyethyl) groups. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 37: 472–482, 2005

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