Synthesis of Pincer-Type Bis(benzimidazolin-2-ylidene) Palladium Complexes and Their Application in C−C Coupling Reactions
✍ Scribed by Hahn, F. Ekkehardt; Jahnke, Mareike C.; Pape, Tania
- Book ID
- 120465377
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 86 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The picoline‐functionalized benzimidazolium salts __N__‐alkyl‐__N′__‐picolylbenzimidazolium bromide [alkyl = methyl (**1**), ethyl (**2**), __n__‐propyl (**3**), __n__‐butyl (**4**)] and the dipicoline‐functionalized benzimidazolium bromide **5** have been synthesized. Reaction of the s
## Abstract Symmetrically and unsymmetrically substituted benzimidazolium bromides (1a–d = NHC·HBr) were synthesized, incorporating bulky benzyl and/or methoxyethyl substituents (a: R = pentamethylbenzyl, R′ = 2‐methoxyethyl; b: R = 2,3,5,6‐tetramethylbenzyl, R′ = methoxyethyl; c: R, R′ = pentameth