𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of phosphorus-substituted dialkylamides of organophosphorus acids, containing P–C–N–P moiety

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Book ID
102231980
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
257 KB
Volume
19
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Reactions of N‐(trimethylsilyl)amino‐methylphosphonates with organophosphorus acid chlorides were studied, which allowed to develop convenient synthetic approaches to novel phosphorus‐substituted dialkylamides of organophosphorus acids, including a P–C–N–P moiety. Certain properties of the resulting compounds are presented. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:495–499, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20468

📜 SIMILAR VOLUMES

Synthesis of Stable N′,N′,N′′,N′′-Tetram
Synthesis of Stable N′,N′,N′′,N′′-Tetramethylguanidine-Substituted σ4(P)- and σ3(P)-Organophosphorus Compounds with N-Protonated P–N Bonds - The First σ3-Phosphorus-Substituted Ammonium Salts☆
✍ Volker Plack; Jochen Münchenberg; Holger Thönnessen; Peter G. Jones; Reinhard Sc 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 559 KB

The dependence of the protolytic decomposition rate of triphenylmethylphosphonous dichloride 1 was allowed to react with 3 equivalents of HTMG, forming the stable phosphorus amides on the substituents at phosphorus is decribed. On treatment with HCl, the NЈ,NЈ,NЉ,NЉ-phosphonium salt 19, soluble in w