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Synthesis of Phosphorus Esters by Transesterification Mediated by N-Heterocyclic Carbenes (NHCs).

✍ Scribed by Rohit Singh; Steven P. Nolan

Publisher
John Wiley and Sons
Year
2006
Weight
20 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Michael G. Organ; Mirvat Abdel-Hadi; Stephanie Avola; Igor Dubovyk; Niloufar Had 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 395 KB 👁 1 views

## Abstract Pd–N‐heterocyclic carbene (NHC)‐catalyzed Buchwald–Hartwig amination protocols mediated by Pd–PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized drug‐like aryl amines in high yield with both electron‐deficient and electron‐rich ary