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Synthesis of phosphorus-containing polyurethanes from oligoethers prepared from bis(chloromethyl) methylphosphine oxide and glycols

✍ Scribed by G. Borissov; S. Varbanov; B. Zaphirova


Book ID
103073882
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
298 KB
Volume
10
Category
Article
ISSN
0014-3057

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✦ Synopsis


Abstraet--Oligoethers with hydroxyl end-groups were prepared in boiling toluene from bis(chloromethyl)methylphosphine oxide and glycols used as monosodium glycolates. From these oligoethers and diisocyanates (hexamethylenediisocyanate and 2,4-toluene-diisocyanate), phosphorus-containing polyurethanes were synthesized.


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Preparation of phosphorus-containing pol
✍ M. Sato; M. Yokoyama 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 316 KB

Phosphorus-containing polyamide-imides were prepared from N,N'-bis(4-carboxyphthalimido)-3,Y-diphenylalkylphosphine oxide and aromatic diacetamido derivatives by acidolysis; the reaction conditions are discussed. The resulting polymers were fairly soluble in DMA, DMF and conc. H2SO4; the reduced vis