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Synthesis of phosphine-borane complexes of P-heterocycles

✍ Scribed by György Keglevich; Kálmán Újszászy; Áron Szöllősy; Krisztina Ludányi; László Tőke


Book ID
103231184
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
550 KB
Volume
516
Category
Article
ISSN
0022-328X

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Synthesis of functionalised cyclohexadie
✍ Carmen M. Andújar Sánchez; Ma̱ José Iglesias; Fernando López Ortiz 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 143 KB

Functionalised 1,3-and 1,4-cyclohexadienes have been prepared through dearomatisation of benzonitriles by sequential conjugate addition of a-lithium alkyl(diphenyl)phosphine borane in the presence of HMPA and capture of the intermediate anion with protonating and alkylating reagents.