𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of Pheromones with Acetal Structures via Radical CC Bond Formation

✍ Scribed by Giese, Bernd ;Bartmann, Dieter ;Haßkerl, Thomas

Book ID
102367571
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
288 KB
Volume
1987
Category
Article
ISSN
0947-3440

No coin nor oath required. For personal study only.

✦ Synopsis

Spirocyclic acetals 4% 4b and exo-brevicomin (5) are synthesized as racemates via radical additions to divinyl ketone and methyl vinyl ketone, respectively. Radical precursors are the alkyl mercuric salt 6 and iodides 9a, 9b. which can easily be generated via

📜 SIMILAR VOLUMES

PATAI'S Chemistry of Functional Groups |
PATAI'S Chemistry of Functional Groups || Iron-Catalyzed CC Bond Formation with CH Bond Activation
✍ Rappoport, Zvi 📂 Article 📅 2012 🏛 John Wiley & Sons, Ltd 🌐 English ⚖ 365 KB

Searchable, Updating Database Containing Volumes Of Patai's Chemistry Of Functional Groups (including Those Issued Under Its Earlier Titles: Chemistry Of Functional Groups, And: Patai Series) Published From 1996 To The Present. Began In 2010 Or 2011. Title From Table Of Contents Page (viewed June 9,

Diastereoselective synthesis of branched
Diastereoselective synthesis of branched 2-deoxy sugars via radical c-c bond formation reactions
✍ Bernd Giese; Kay Gröninger 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 201 KB

From glycals l and 5, 2-deoxy sugars can be synthesized in 40-728 yields. With 1,2\_disubstituted alkenes 1 this radical C-C bond formation reaction leads with high stereoselectivity to the isomers The formation of C-C bonds via solvomercuration of electron-rich alkenes and reduction with hydrides i