A new synthesis of 3-substituted-1H-indenes has been developed through the reaction of o-(b-magnesioalkyl)phenylmagnesium dihalides with carboxylate esters, followed by dehydration of the intermediate 1-substituted-1-indanols. Di-Grignard reagents allowing the synthesis of 3-substituted-, 2-methyl-3
Synthesis of phenylmagnesium carboxylates
β Scribed by Pramesh N. Kapoor; Ajay K. Bhagi; Harish K. Sharma; Ramesh N. Kapoor
- Book ID
- 107811371
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 236 KB
- Volume
- 369
- Category
- Article
- ISSN
- 0022-328X
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The authors regret that the value of the Gibbs energy of activation for the atropisomerisation of compound 20 (minor to major diastereoisomer) at 288 K was incorrectly given as 23.3 kcal mol -1 . The actual value is 22.9 kcal mol -1 . PII of original article: S 0 0 4 0 -4 0 3 9 ( 0 2 ) 0 2 3 4 4 -4
Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific A