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Synthesis of Phenyl-Substituted Conduritol B and Its Mechanism of Formation

✍ Scribed by Seda Cantekin; Raşit Çalışkan; Ertan Şahin; Metin Balci

Book ID: 102256798
Publisher: John Wiley and Sons
Year: 2007
Tongue: German
Weight: 357 KB
Volume: 90
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.200790231

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✦ Synopsis

Abstract

The phenyl‐substituted conduritol B 8 was prepared in racemic form in a five‐step sequence starting from 2‐phenyl‐1,4‐benzoquinone (10) (Scheme 1). The reaction mechanism of the key step 12b→13 is discussed (Scheme 2).

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