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Synthesis of phenoxy-substituted spiro-ansa phosphazene derivatives

✍ Scribed by Saliha Begeç

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
117 KB
Volume
18
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

In this study, reactions of 2,4,4,6,6‐pentachloro‐2‐(2,4,6‐trimethylphenoxy)cyclo‐2λ^5^,4λ^5^,6λ^5^‐triphosphazatriene (1) and 2,4,4,6,6‐pentachloro‐2‐(2,4,6‐tritertbutylphenoxy)cyclo‐2λ^5^,4λ^5^,6λ^5^‐triphosphazatriene (2) with 2,2′‐dihydroxybiphenyl (3) in acetone in the presence of potassium carbonate have been investigated. Mono ansa (4) and spiro‐ansa (5) derivatives were obtained from of 3 with 1, while mono spiro (6) and mono ansa (7) derivatives were obtained from 2. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:372–375, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20322

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