The radical polyaddition of N-4-vinylbenzoyl-L-cysteine methyl ester (VCM) was carried out in the presence of 2,2Ј-azobisisobutyronitrile (AIBN, 3 mol %) as an initiator in dimethyl formamide (DMF) with monomer concentrations of 0.5 and 1.0 M at 60 °C for 20 h under nitrogen atmosphere to afford the
Synthesis of phenetidine-based telechelics and subsequent reactions with water-based curing reagents
✍ Scribed by Tito Viswanathan; Janna Helmich; Stephen Rodriguez; Qiuwei Feng; Alan Toland
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 214 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
The development of soluble telechelics based on aniline are highly desirable due to numerous applications that are possible, especially in the coatings and adhesive industry. Control of molecular length and ease of synthesis lends o-ethoxyaniline to be an ideal candidate for the synthesis of amino-terminated telechelic oligomers. Combined with the higher solubility and reactivity, curing of these functionally reactive oligomers has been accomplished using aqueous formaldehyde, as well as water-dispersed epoxy resins. Spectroscopic studies have been done to characterize the prepolymers, as well as the cured materials.
📜 SIMILAR VOLUMES
## Abstract UV curable telechelic urethane–methacrylate crosslinkers based on the natural resource—cardanol was synthesized in a one pot synthetic step involving end capping of isophorone diisocyanate with one equivalent of hydroxyethyl methacrylate followed by condensation with cardanol. The struc