## Abstract Novel covalent fullerene C~60~–perylene‐3,4:9,10‐bis(dicarboximide) (C~60~–PDI) dyads (1–4) were synthesized and characterized. Their electrochemical and photophysical properties were investigated. Electrochemical studies show that the reduction potential of PDI can be tuned relative to
✦ LIBER ✦
Synthesis of Perylene-3,4-mono(dicarboximide)−Fullerene C60 Dyads as New Light-Harvesting Systems
✍ Scribed by Baffreau, Jérôme; Ordronneau, Lucie; Leroy-Lhez, Stéphanie; Hudhomme, Piétrick
- Book ID
- 111859942
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 434 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
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Several pyrrolidinofullerenes were N-arylated by phase-nitro groups on the N-phenyl ring have a strong influence on the reduction potential values. Theoretical calculations at the transfer catalysis in the absence of solvent. The electrochemical behaviour of the novel C 60 -acceptor dyads semiempiri