Synthesis of perfluoro-1-enyl aryl ketones from aroylsilanes and perfluoroalkyliodides

✍ Scribed by B. Dondy; C. Portella

• Book ID: 104150519
• Publisher: Elsevier Science
• Year: 1991
• Tongue: English
• Weight: 33 KB
• Volume: 54
• Category: Article
• ISSN: 0022-1139
• DOI: 10.1016/s0022-1139(00)83792-6

✦ Synopsis

Perfluoroorganometallic

reagents reacted with aroylsilanes to lead, according to the experimental conditions and the nature of the metal, to alcohols 1 or enones zl.

We will demonstrate in this communication that perfluoroorganomagnesium derivatives are very versatiles reagents. By adjusting experimental conditions, only enones 2 were obtained in excellent yields in a simple one pot procedure. On the other hand, these enones can also be obtained by a catalytic way from alcohol I.