✦ LIBER ✦

Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica

✍ Scribed by Ilhyong Ryu; Sergio Kreimerman; Tatsuro Niguma; Satoshi Minakata; Mitsuo Komatsu; Zhiyong Luo; Dennis P Curran

Book ID: 104211647
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 62 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02153-5

No coin nor oath required. For personal study only.

✦ Synopsis

A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS).

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of Perflu

ChemInform Abstract: Synthesis of Perfluorinated Allylic Compounds by Radical Allylation and Their Purification over Fluorous Reverse-Phase Silica.

✍ Ilhyong Ryu; Sergio Kreimerman; Tatsuro Niguma; Satoshi Minakata; Mitsuo Komatsu 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 28 KB

ChemInform Abstract: Synthesis of Perflu

ChemInform Abstract: Synthesis of Perfluoroalkyl-Substituted Aryl Bromides and Their Purification over Fluorous Reverse Phase Silica.

✍ S. KAINZ; Z. LUO; D. P. CURRAN; W. LEITNER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Thermal Allylations of Aldehydes with a

Thermal Allylations of Aldehydes with a Fluorous Allylstannane. Separation of Organic and Fluorous Products by Solid Phase Extraction with Fluorous Reverse Phase Silica Gel †

✍ Curran, Dennis P.; Hadida, Sabine; He, Mu 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 72 KB

ChemInform Abstract: Thermal Allylations

ChemInform Abstract: Thermal Allylations of Aldehydes with a Fluorous Allylstannane. Separation of Organic and Fluorous Products by Solid Phase Extraction with Fluorous Reverse Phase Silica Gel.

✍ D. P. CURRAN; S. HADIDA; M. HE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB