## Abstract A series of pyrimidinyl benzylamine analogues containing a phosphonyl group (**2**) was synthesized via the Mannichβtype reactions of 2β(4,6βdimethoxypyrimidinβ2βyloxy)benzoaldehyde **1**, aromatic amines, and dialkyl phosphites or triphenyl phosphite in the presence of Mg(ClO~4~)~2~. T
β¦ LIBER β¦
Synthesis of pentacoordinated germanium compounds containing a phosphonyl group
β Scribed by Ruyu Chen; Lunzu Liu; Zhongbiao Zhang
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 259 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1042-7163
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β¦ Synopsis
The title compounds were prepared by the reaction of germanium sesquioxides with diethyl N, N-bis(2-hy-droxyethy1)aminomethylphosphonate in good yields (72-94%). The X-ray analyses showed that the geometry about the germanium atom was a distorted trigonal bipyramid.
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