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Synthesis of pentacoordinated germanium compounds containing a phosphonyl group

✍ Scribed by Ruyu Chen; Lunzu Liu; Zhongbiao Zhang


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
259 KB
Volume
6
Category
Article
ISSN
1042-7163

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✦ Synopsis


The title compounds were prepared by the reaction of germanium sesquioxides with diethyl N, N-bis(2-hy-droxyethy1)aminomethylphosphonate in good yields (72-94%). The X-ray analyses showed that the geometry about the germanium atom was a distorted trigonal bipyramid.


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## Abstract A series of pyrimidinyl benzylamine analogues containing a phosphonyl group (**2**) was synthesized via the Mannich‐type reactions of 2‐(4,6‐dimethoxypyrimidin‐2‐yloxy)benzoaldehyde **1**, aromatic amines, and dialkyl phosphites or triphenyl phosphite in the presence of Mg(ClO~4~)~2~. T